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1 article(s) from Liu, Run-Zhou

A Streptomyces P450 enzyme dimerizes isoflavones from plants

Run-Zhou Liu,
Shanchong Chen and
Lihan Zhang

Beilstein J. Org. Chem. 2022, 18, 1107–1115, doi:10.3762/bjoc.18.113

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Figure 1: Structures of cattleyaisoflavones A (1), B (2), C (3), and daidzein (4).

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Figure 2: a) The culture in ISP-2 liquid did not produce 1–3, while feeding with 4 restored the production (a...

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Figure 3: CYP158C1 dimerizes 4 to form dimers 2 and 5 in vitro (analytical method B, 254 nm). Control conditi...

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Scheme 1: a) Compatible and b) incompatible substrates of CYP158C1. Products were identified using analytical...

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Scheme 2: Proposed mechanism of CYP158C1-mediated dimerization of isoflavones.

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Published 26 Aug 2022

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